![]() ![]() Web: Atlantic City International (ACY) airport on map -locationĪtlantic City International Airport (ACY) is located near the Atlantic City in the state New Jersey. The single-step rate law approximation of a reversible reaction leads to T 0 = H°/Δ S° as the dynamic thermal (thermodynamic) equilibrium temperature and 1/ T 0 = (ln)/( E̅/ R) as the slope of a Constable/KCE plot or the crossover temperature of Arrhenius lines in an isokinetic relationship (IKR), where A̅ and E̅ are mean values for the ensemble of compensating pairs in the literature, and the difference in the standard enthalpies and entropies of formation of the products and reactants for thermal decomposition of organic peroxides, calcium carbonate, and poly(methyl methacrylate).Atlantic City airport contacts: adress, zip code, phoneĪdress: 101 Atlantic City International Airport, Egg Harbor Township, NJ 08234, USA In this paper, it is suggested that the linear relationship between ln and E is the result of a real or spurious path dependence of the reaction history between the initial state of the pure reactant(s) and the final state of the pure product(s) having standard enthalpy and entropy differences, Δ H° and Δ S°, respectively. The kinetic compensation effect (KCE) is demonstrated by a linear relationship between ln and E/ R in the eponymous Constable plot and has been the subject of more than 50 000 publications over the past 100 years, with no consensus opinion about the cause of this effect. Kinetic compensation is a strong, positive correlation between the Arrhenius activation energy E and the frequency factor A for a reaction between the same reactants under similar experimental conditions or similar reactants under the same conditions, even though these parameters are supposed to be independent. ![]()
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